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Print version record.;Cover; Preface; Contents; Recent developments and applications of Lewis acidic boron reagents; 1 Introduction to Lewis acidic boron compounds; 2 Synthesis of Lewis acidic boron reagents; 3 Applications of novel boranes and borocations; 4 Advanced applications of Lewis acidic boron reagents; 5 Main group catalysis using boron reagents; 6 Conclusions; References; Masked low-coordinate main group species in synthesis; 1 Scope; 2 Notes; 3 Introduction; 4 Masking strategies; 5 A diversion: group 12; 6 Low-coordinate monomers of group 13 elements; 7 Low-coordinate dimers of group 13 elements.;8 Low-coordinate monomers of group 14 elements9 Low-coordinate dimers of group 14 elements; 10 Low-coordinate monomers of group 15 elements; 11 Low-coordinate dimers of group 15 elements; 12 Low-coordinate main group heterodimers; 13 Conclusion; References; The diiron centre: Fe2(CO)9 and friends; 1 Introduction; 2 Fe2(CO)9: structure; 3 Fe2(CO)9: bonding and electron-counting; 4 Fe2(CO)9: in solution; 5 Unsaturated derivatives Fe2(CO)x x=8-6; 6 Isoelectronic derivatives Fe2(CO)82- and HFe2(CO)8-; 7 Radical anions Fe2(CO)x- and cations Fe2(CO)x+;8 Derivatives of Fe2(CO)9 and Fe2(CO)82-: general comments9 Replacement of bridging carbonyl(s): Fe2(CO)6(µ-CO)3-n(µ-X2)n; 10 Derivatives with bidentate ligands: Fe2(CO)6(µ-CO)(µ-L2) and Fe2(CO)5(ƙ2-L2)(µ-CO); 11 Derivatives of Fe2(CO)82-: Fe2(CO)8(ƙ1-X)2 and Fe2(CO)6(ƙ1-LX)2; 12 Fe2(CO)6(µ-S2) and related chalcogenide complexes; 13 Diaazo-bridged complexes Fe2(CO)6(µ-RNNR) and phosphorus analogues; 14 Thionitroso Fe2(CO)6(µ-RNS) and alkyne Fe2(CO)6(µ-RCCR) complexes; 15 Fe2(CO)6(µ-CO)(µ-LX)-; 16 Fe2(ɳ4-C4R4)2(µ-CO)3 and related terminally substituted derivatives; 17 Concluding remarks;ReferencesTaddol and Binol-derived chiral phosphonites in asymmetric catalysis; 1 Introduction; 2 Stereoelectronic profile of phosphonites; 3 Taddol-derived chiral phosphonites; 4 Binol-derived chiral phosphonites; 5 Conclusion; Acknowledgments; References; Gold-catalysed C-F bond activation; 1 Introduction; 2 Gold catalyses C-F bond activation; 3 Summary and outlook; Acknowledgments; References; Silylamides: towards a half-century of stabilising remarkable f-element chemistry; 1 Introduction and scope of the review; 2 Low coordination number complexes; 3 Reactivity; 4 Multiple bonds.;5 ConclusionsReferences. Providing an invaluable volume, Organometallic Chemistry Volume 41 contains analysed, evaluated and distilled information on the latest in organometallic chemistry research.

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